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1.
Xing LU Yue WANG Hai Yuan ZHANG Chun Ji NIU* Jia Zuan NI Key Laboratory of Rare Earth Chemistry Physics Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun 《中国化学快报》2001,(9)
With the wide application of rare earth fertilizer and medicines1, more and more rare earths enter into environment, and also into human body via food chain. Now it is very urgent to study the biological effect of rare earths on human health and environment. After entering into human body by whatever route, lanthanide ions are transported to secondary deposition sites mainly via the plasma in the blood stream. So it is very important to study lanthanides speciation in human blood plasma. Becau… 相似文献
2.
The TiO2 gel doped with UO22 and Eu3 has been prepared by a sol-gel method. The quenching of the UO22 emission by Eu3 and the energy transfer from the excited state of UO22 to the ground state of Eu3 have been investigated. The energy transfer has been studied by the measurement of luminescence lifetime τ, calculations of energy transfer efficiency ηET and energy transfer rate WET. The experimental results indicated that the quenching is combined static and dynamic mechanism, but the static mechanism is dominant. 相似文献
3.
Zhi Jian WU* Si Yuan ZHANG Laboratory of Rare Earth Chemistry Physics Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun 《中国化学快报》2000,(12)
HgBa2Can-1CunO2n+2+( (n=1, 2, 3, 4) 1 are tetragonal with space group space P4/mmm. For n=1,2,3, nearly single-phase crystals were obtained, while for n=4, the sample was primarily a mixture of the n=3 and 4 phases. These materials also possessed the highest Tc values yet observed for any superconductors. In this paper, the valences of elements in the title compounds were calculated from bond valence sum method 2. The calculated bond covalency, valences of elements were summarized in Table … 相似文献
4.
Phosphor of KMgF_3:Ce~(3+)is synthesized through solvothermal method at 180℃and characterized by means of X-ray powder diffraction(XRD)and environment scanning electron microscopy(ESEM).X-ray photoelectron spectroscopy(XPS)is applied to the study of the energy band structure of KMgF_3:Ce~(3+)and confirms the oxygen content of the product is very low.The fluorescence spectra of the rare-earth ion-doped KMgF_3 is investigated by the fluorescence spectrophotometer.In the emission spectra,there is a broadban... 相似文献
5.
YAN Jing-hui ZHANG Hai-yan LI Zhong-tian CAO Jie SONG Li-hong ZHANG Hui-qiu SHI Chun-shan.College of Chemistry Environmental Engineering Changchun University of Science Technology Changchun P.R.China .Key Laboratory of Rare Earth Chemistry Physics Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun P.R.China 《高等学校化学研究》2007,(4)
Nanocrystals of KMgF3 single-doped and codoped with Ce3 or/and Yb3 were synthesized separately by the microemulsion method.The X-ray diffraction(XRD)patterns were indexed to show that the KMgF3 crystal system was unchanged.The fluorescent spectra of KMgF3∶Ce,Yb polycrystal powders were studied and compared with those of the Ce,Yb doped KMgF3 crystals produced using the high-temperature solid phase method.The diffuse reflection spectra and infrared emission of KMgF3∶Ce,Yb were investigated.From the results,the authors could confirm that there were charge transfer processes from Ce3 to Yb3 in both KMgF3∶Ce,Yb nanocrystals and polycrystal powders. 相似文献
6.
用TG-DTA,高温X-射线衍射研究了稀土间硝基苯甲酸配合物LnL_3·nH_2O(n=2,Ln=La→Lu+Y;n=0,Ln=Sc,HL=间硝基苯甲酸)的热分解行为,DSC测定其脱水相变过程中的热力学函数,同时用透射电镜观察了热分解产物的超微性。 相似文献
7.
PENG Zi-cheng LI Ping ZHOU Tai-xi LI Xue-ming Wept. of Earth Space Science Univ. of Science Tech. of China Hefei )HU Zhi-sheng 《高等学校化学研究》1992,(3)
When was the earliest glass produced in China? This has still been a question so far. Some archaeologists have thought that Yu Guo beads are real glass, the earliest glass(1100-771 B. C. ) in China. However, more details of scientific investigations in this paper show that Yu Guo beads are mainly made of clastic quartz (>95%) with a small amount of clay and sintered under the low temperature(500-600℃). It is not a glassy body, but a kind of polycrystal ornaments. 相似文献
8.
测定了二(2,4,4-三甲基戊基)膦酸(BTMPPA)及其稀土配合物Ln(BTMPP)3在4000~50cm^-1光谱区内的FT-IR光谱和部分配合物的激光拉曼光谱,对其谱带进行了经验归属。发现稀土氧键具有较高的离子键特性。由Ln-O伸缩振动频率值算出其近似力常数约8m dyn/nm。 相似文献
9.
<正>We describe a mobile molecular Doppler wind lidar(DWL) based on double-edge technique for wind measurement of altitudes ranging from 10 to 40 km.A triple Fabry-Perot etalon is employed as a frequency discriminator to determine the Doppler shift proportional to the wind velocity.The lidar operates at 355 nm with a 45-cm-aperture telescope and a matching azimuth-over-elevation scanner that provides full hemispherical pointing.To guarantee wind accuracy,a single servo loop is used to monitor the outgoing laser frequency to remove inaccuracies due to the frequency drift of the laser or the etalon.The standard deviation of the outgoing laser frequency drift is 6.18 MHz and the corresponding velocity error is 1.11 m/s.The wind profiles measured by the DWL are in good agreement with the results of the wind profile radar(WPR).Evaluation is achieved by comparing at altitudes from 2 to 8 km.The relative error of horizontal wind speed is from 0.8 to 1.8 m/s in the compared ranges.The wind accuracy is less than 6 m/s at 40 km and 3 m/s at 10 km. 相似文献
10.
Two guanidino acid oxovanadium(Ⅳ) complexes have been synthesized. Preliminary tests in vivo have shown that the two title complexes all display lowering glucose activity in vivo to STZ-rats. The effect of glucose-lowering of guanidino acetic acid oxovanadium(Ⅳ) complex in vivo is higher than that of guanidino propanoic acid oxovanadium(Ⅳ) complex. 相似文献